In order to get some feeling for why the scale was organized in this way, we will make use of some physical features of any sounds, especially continuous sounds, which make up the experience we call a pitch. A note with a definite pitch tends to be a sound with a definite repetition in time, a definite period. However such notes are almost never pure sinusoids- they have a more or less complex shape when one views the pressure distribution in the note as a function of time. We have learned that such a complex distribution of pressure can always be represented by a sum of pure sinusoidal sounds, a fundamental, which has the same fundamental period as the sound, and its various harmonics (frequencies which are integer multiples of that fundamental frequency).
One of the most astonishing feature of human hearing is that that huge set of disparate frequencies ( and we know that those different frequencies excite different parts of the basilar membrane, and send signals down different nerves to the brain- almost as if the ear were doing a Fourier analysis of the sound, and reporting to the brain about each of the separate sinusoidal frequencies that make up the complex sound) are experienced by us as a single pitch. Those separate components are amalgamated in the brain as a single pitch, with the different amplitudes changing the "tone-colour" of the note, but not the pitch or the unity of the experience of that sound. Ie, it seems that the brain tried to amalgamate frequencies which are integer multiples of each other into a single sound experience.